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Gewählte Publikation:

Weber, J; Mikula, H; Fruhmann, P; Hametner, C; Varga, E; Berthiller, F; Krska, R; Frohlich, J.
(2013): Gentiobiosylation of beta-Resorcylic Acid Esters and Lactones: First Synthesis and Characterization of Zearalenone-14-beta,D-Gentiobioside
SYNLETT. 2013; 24(14): 1830-1834. FullText FullText_BOKU

The development of an optimized protocol for the gentiobiosylation of beta-resorcylic acid esters and lactones (beta-RAL) is presented. Different gentiobiosyl donors were prepared and used for regioselective and diastereoselective glycosylation affording a reliable synthetic strategy towards this class of natural product glycosides. The improved procedure was finally used for the preparation of the masked Fusarium mycotoxin zearalenone-14-beta,D-gentiobioside.
Autor*innen der BOKU Wien:
Berthiller Franz
Krska Rudolf
Varga Elisabeth
BOKU Gendermonitor:

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natural products

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