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Gewählte Publikation:

Zaccaron, S; Potthast, A; Henniges, U; Draxler, J; Prohaska, T; McGuiggan, P.
(2019): The disastrous copper. Comparing extraction and chelation treatments to face the threat of copper-containing inks on cellulose
CARBOHYD POLYM. 2019; 206: 198-209. FullText FullText_BOKU

Abstract:
Iron gall inks are known to be detrimental to the permanence of historic documents. Among the transition metals present, copper is the greatest threat and an open challenge due to the lack of Cu-specific treatments. In this study, we address the inhibition of copper by comparing extraction (a newly proposed glucose-based treatment) vs. chelation (phytate-based) approaches in terms of performances in scavenging copper and slowing the degradation rate, and of possibly induced side effects. Results show that the glucose treatment partially extracts copper, but it causes long-term damages to paper, i.e. increased fragility and discoloration. The phytate protocol was found beneficial in inhibiting the catalytic activity of copper-rich inks. It limits both long-term oxidation and hydrolytic breakdown of samples without compromising the visual appearance.
Autor*innen der BOKU Wien:
Draxler Johannes
Henniges Ute
Potthast Antje
Prohaska Thomas
Zaccaron Sara
BOKU Gendermonitor:


Find related publications in this database (Keywords)
Cellulose
Iron-gall inks
Copper-catalysed degradation
Calcium phytate
Reducing sugars
Oxidation


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