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Gewählte Publikation:

Röhrling, J., Potthast, A., Rosenau, T., Lange T., Borgards, A., Sixta, H., Kosma, P..
(2001): Synthesis and testing of a novel fluorescence label for carbonyls in carbohydrates and cellulosics.
Synlett., 5, 682-684

A carbonyl-selective fluorescence label 5 for the detection of oxidized groups has been synthesized by an expeditious three-step sequence. The fluorophore carbazole and the reactive aminoxy group, which binds to carbonyls as an oxime, were tethered by a diethylene glycol spacer. The label allows detection of minute amounts of oxidized functionalities in oligosaccharides and cellulosics under the relatively harsh conditions of GPC separation, without fluorescence interference with light scattering (MALLS) detection. Synthetic keto sugars have been used to optimize the derivatization reaction.
Autor*innen der BOKU Wien:
Kosma Paul
Potthast Antje
Rosenau Thomas
BOKU Gendermonitor:

Find related publications in this database (Keywords)
keto sugars
fluorescence labeling

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