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Selected Publication:

Krongtaew, C; Messner, K; Ters, T; Fackler, K.
(2010): CHARACTERIZATION OF KEY PARAMETERS FOR BIOTECHNOLOGICAL LIGNOCELLULOSE CONVERSION ASSESSED BY FT-NIR SPECTROSCOPY. PART I: QUALITATIVE ANALYSIS OF PRETREATED STRAW
BIORESOURCES. 2010; 5(4): 2063-2080.

Abstract:
Wheat straw (Triticum aestivum L.) and oat straw (Avena sativa L.) were subjected to acid and alkaline pre-treatments partly in combination with hydrogen peroxide. The aim was to remove lignin and increase the accessibility of the polysaccharides to enzymatic digestion. Accessibility was evaluated by digestion with a cell wall degrading enzyme complex to yield reducing sugars that may serve as precursor substrates for biofuels or building block chemicals. Changes in lignin, hemicelluloses, as well as amorphous, semi-crystalline, and crystalline regions of cellulose moieties of pretreated straw were efficiently characterized by Fourier transform near-infrared (FT-NIR) reflectance spectroscopy. These alterations of the chemical structure of straw after different pre-treatment methods were powerfully differentiated by principal component analysis (PCA). Characteristics of the different samples owing to the different pretreatment methods could be clustered from the PCA loadings spectra.
Authors BOKU Wien:

Find related publications in this database (Keywords)
Lignocellulose characterization
Wheat and oat straw
Mild acidic and alkaline peroxide pretreatments
Fourier-transform near infrared spectroscopy (FT-NIR)
Principal component analysis (PCA)
Multivariate data analysis
Qualitative discriminant analysis


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