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Selected Publication:

Rosenau, T; Potthast, A; Krainz, K; Yoneda, Y; Dietz, T; Shields, ZPI; French, AD.
(2011): Chromophores in cellulosics, VI. First isolation and identification of residual chromophores from aged cotton linters
CELLULOSE. 2011; 18(6): 1623-1633. FullText FullText_BOKU

Abstract:
In the present work, aged cotton linters have been analyzed for their chromophore content according to the CRI ("chromophore release *** identification") method. Despite the very low contents in the ppb range, nine chromophores have been unambiguously identified, which makes this account the first one on defined chromophoric structures isolated from cotton. A common feature of the chromophores are 2-hydroxy-[1,4] benzoquinone, 2-hydroxyacetophenone and 5,8-dihydroxynaphthoquinone moieties, which resemble chromophoric structures found in other cellulosic substrates, such as bleached pulps or fibers. The finding of these compounds in lignin-free cotton linters confirms the previous hypothesis that those chromophores are formed from (oxidized) carbohydrate structures rather than from lignin fragments.
Authors BOKU Wien:
Potthast Antje
Rosenau Thomas

Find related publications in this database (Keywords)
Cellulose
Cotton
Chromophores
Aging
Bleaching
CRI method
Hydroxybenzoquinones
Hydroxynaphthoquinones
Hydroxyacetophenones
Quantum mechanics


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